Accolade time. Solid foundations indeed. Pity I can't move my leak to Bonnie Scotland and you're far too established to move darn sarf.
The more this goes on, the more clarity emerges re. the solution. I'm never rash (doesn't work for me; errors occur) and if anything I overdo the caution bit. My exp. tank was cleaned out by me 18 months ago (had been done a couple of previous times, years apart).
One of the plumbers told me on installation that the tank was clean (he was up there and I took him at his word). Before sealant was put in nearly 4 weeks ago I fully cleaned the tank which had a fair thickness of rust-coloured residue on the bottom + sides. Have just been up and there's a coating of the same on the bottom of the tank. The milky sealant mix is now clear so all is clear.
Bleeding one or two rads at odd times over the past couple of months threw out rusty coloured water after air, but now clear. I think I can deduce from this that (a) the cleaner was very aggressive (Magnclean) and (b) that iron pipes/solder/fittings/whatever under the concrete have been eroding for years but much more recently. Pretty sure I noticed an iron pipe back in '09, but maybe that was for gas; didn't pay attention at the time despite being manually involved in the excavations.