FWIW I have tried a lot of very rare and expensive valves in my Stereo 20 and not found anything I’d take over a genuinely good set of Mullards. I do really like the Russian military 6P14P-ER or EV though so whilst I have a very strong (possibly NOS) set of 1964 yellow print Mullards I tend to run the Russian ones to save the Mullards. The Russian ones are more forward, the Mullards create a bigger deeper soundstage. Both good.
Also worth baring in mind that there are five or six completely different Mullard ECC83s and getting on for that with GZ34s. A few variations of EL84s too. The thing to look at is the etched code. This gives the valve type e.g. ECC83 MC1, F91 (both long-plates), I61, I63 plus whatever the Mitchum box-plate was called (I’ve got one, its in my guitar amp!) etc. They all sound very, very different from highly dynamic and a touch forward to the stereotypical warm sound people who’ve only heard ‘70s Mullards cite as the character. Many variables. There are changes within type, e.g. an early I63 with copper rods sounds different/better to a much later ones with nickel. One can get quite obsessive about such things. I seem to have been very lucky, Mullards seem to find their way to me to the extent I’ve likely got 15-20 or so nice ECC83s of differing eras, mostly from random auction lots or in other equipment. Same with GZ34s, I have enough not to worry now.
PS Regarding the EIs Jez mentioned: the silver-plates are a very nice sounding valve (grey plates far less so, but still decent). The problem is reliability, every single one I’ve owned, and its been a fair few, went noisy or microphonic after not too long. You’ll end up spending far more cash on those than a ‘60s Mullard which will almost certainly outlive ten of them!