Tim,
Even with a 5% zener tolerance the voltage should be no more than about 64.3 volts. The TPR feeds a consistent 12.5mA into the load, set by the 100R of course, and you might want to increase that resistor to something like 220R to give the voltage setting regulator something to do, i.e. regulate, depending upon the load current drawn. If you have one per front end channel then that might be the reason for the higher than expected voltage.
John