OK,
Understand that a bucking transformer is NOT ISOLATED from the mains. It carries FULL mains voltage on both the primary (240v) and secondary (20v) windings. You must make sure you cannot come into contact with any part of it at any time. It will kill you...
You will also need a multi-meter that can measure mains and output voltages.
Look at the left side Figure 4 on the Elliott Sound Products page above.
This is what you are trying to do. You have a transformer with a 240 volt mains (primary) winding. You use the 20 volt secondary winding and add that 'on top' of the primary.
If you look at the diagram you will see the AC IN (live) goes first to the 20 volt connection, through the 20 volt winding then to the top of the 240 volt winding, through that back to the other AC IN (neutral).
You have actually made a 260 volt transformer, but your mains is still only 240 volts, so where the 20 volt and 240 volt windings join (AC OUT on the diagram) you get 240 minus 20 = 220 volts.
BUT, only if you have the windings in the correct relationship. (That is what the small black dots on the diagrams signify) Unless you know the winding direction, you have a 50/50 chance of ending up with more than 240 volts output!
I doubt your transformer will be marked, so you have to measure your results BEFORE using it. If you measure about 220 volts between the AC OUT positions all is well. If you measure More than 240 volts there, swap the two 20 volt wires round and measure again.
As your transformer has a centre tap Only connect one half (if that is 20 volts) and carefully insulate the other connection. (Do Not join the 20 volt ends together, that will just short the transformer out...)
You do not say what current or VA rating your transformer is, or what current the Crimson amp uses, make sure it is actually large enough.
I still do not understand the transformer 'earth' connection, unless it is an internal screen inside the transformer. It might be marked Screen or SCN?
Again, if you have any doubts, please leave it alone.