OK, I mean the *most* volatile portions, if we are going to be pedantic.
The evaporation rates are hugely different. Some blends contain butane, as we all know a gas at room temp. It will coevaporate with the other portions, there's going to be a partition coefficient, various isotropic mixtures, a whole chemistry lesson in there, but some C10-12s will hang around for ever. I saw in a magazine the result of a 2CV left in a barn for 40 years - some fuel was still present, though it had gone brown and oily. Now you're right that a few months in a shed isn't 40 years in a barn but it can and does affect the fuel, I know at first hand. As a kid it was always my job to mow the lawns, getting the mower running in spring was invariably a shit that took all afternoon and often a stripped carb. The fix was to run it until it stopped in October and leave it dry until March. Fresh fuel, a bit of 2T oil, brrrrmmmmm, off it went. If you forgot to do so, oh dear. It's the *most* volatile portions that get a cold engine running.