PigletsDad
My intelligence test came back negative.
It is true as far as I know for all electrolytics , to a greater or less extent.
They depend on a reaction between a metal foil and wet electrolyte. The reaction forms an oxide layer on the foil, so one side of the capacitor is fairly conventional Al + Al2O3 or Ta + Ta2O5. The other electrode is a horrible slurry - the effective electrical position of the electrode depends on wet chemical effects like ion migration, surface charge layers and so on. Higher voltage caps have a thicker oxide layer, so the effects of the wet chemistry are diluted, but still there.
Tants give high capacitance in a given size because Ta2O5 has a high dieletric constant (about 25 from memory), while Al2O3 is only 5 to 6.
Mil-spec just means that they are made for a wider temperature range, and have to pass some ruggedness tests. With some products it just means that the manufacturer does extra tests, and fills in lots of forms - the actual product is often identical to the civil version.
They depend on a reaction between a metal foil and wet electrolyte. The reaction forms an oxide layer on the foil, so one side of the capacitor is fairly conventional Al + Al2O3 or Ta + Ta2O5. The other electrode is a horrible slurry - the effective electrical position of the electrode depends on wet chemical effects like ion migration, surface charge layers and so on. Higher voltage caps have a thicker oxide layer, so the effects of the wet chemistry are diluted, but still there.
Tants give high capacitance in a given size because Ta2O5 has a high dieletric constant (about 25 from memory), while Al2O3 is only 5 to 6.
Mil-spec just means that they are made for a wider temperature range, and have to pass some ruggedness tests. With some products it just means that the manufacturer does extra tests, and fills in lots of forms - the actual product is often identical to the civil version.