I have owned STA25 and STA100 (twice now) as well as all sorts of PP valve amps from EAR (890, 509, V20, 861), Leak (Stereo 20, Stereo 60 and TL12 monoblocks), Leben (CS660p, 1000p), and the fabled Tim de P/Andy Grove 300b amp for WAD, and at one point not just a pair but a quad (for by-amping) of Audion Silver Knight PP300b, just to name a few.
I'm not the biggest fan of single ended amps, mainly because neither Tannoys nor Quads like them very much. I know some people are very happy with them on high efficiency horns and the like. But for me they hold little interest, having been round the houses with them over many years. I've had a few, most recently Silvercore 833C which used transmitter tubes, several 300b amps (including Audion again, Tekton and Audio Note), Unison Research S8 (845 tubes) - possibly the worst amplifer I've ever owned - and assorted other 2A3 and 45 flea power custom jobs. None of which could come anywhere close to the performance of a Radford STA25 into Tannoys.
The STA25 is a fantastic all rounder. The STA100 beats it, the main difference being the bass performance, more 3D depth and detail in the soundstage, and the ability not to run out of steam with tougher speakers than the STA25 is happy with. But the STA25 still manages to run it very close as an overall proposition, so likeable is it and so few its actual flaws. It's just fabulously musical. The STA15 is a great amp, too sounding very similar if a touch sweeter, though facing slightly more limitations when it comes to the speakers it can drive. I believe the main difference is the use of a valve rectifier vs solid state in the STA25.
I think the STA25 is underrated for two reasons: first and by far the main reason is price. People often like to to pay more in the expectation that they will get more for the money, but the fact you can still get a very good one for under £2000k, or a brand new one for not a huge amount more from Radford Revival, means they don't get accorded the esteem they deserve. The fact is into the vast majority of speakers out there (90%+ I would suggest) it will easily toast £15k worth of blingy single ended amp. (I've sat and heard that time after time, to the point where it's quite amusing). By toast I mean provide a far more musical experience, in particular better rhythm, timbre and bass control. Far too many people buy with their eyes - either looking at the casework, or reading the specification or theory behind it - rather than their ears. The second reason is the name. STA25 is not a 25 watt amp, it's a 35watt amp. This actually makes a difference.
I recall being very deflated once, well over 10 years ago now, in a shootout into some freshly rebuilt Quad ESLs, of an STA25 Mk3, Leak Stereo 20, Quad II monoblocks, and my then-new EAR V20 (its retail price being four times what any of the vintage amps could be got for at the time). I assumed the EAR would easily come top (I was using it myself into Quads at that point). Well it didn't. It came a creditable second (in my view anyway), but the STA25 absolutely walked it. The Quads and the Leak were each pleasant enough (the Quads running my EAR fairly close), but nowhere near the Radford in terms of all round ability. I got a big lesson that day.
Anyway call me a Radford fanboy if you like, I don't care!
My (new) STA100, rebuilt/restored by Will at Radford Revival: