I agree with colasblue and nws56 on this one, it doesn't make much sense to do this, even though the guts would fit in a NAP200 case you would have to drill it quite a bit to mount the 250 guts, so even if you put the NAP200 back together that's a lot of the resale value lost, and you would struggle to sell olive 250 guts in a 200 case - Naim buyers are often fussy about big mods, a couple of caps here and there ok, but wholesale changes like this would be a no go for most buyers. Also as nws56 said soundwise it might not be worth it to you. If you want to have a play and have ALL the guts of the olive 250 (xfmr/PSU bridges/PSU caps/wiring and the 4 boards etc etc) you could go for the "holy crap that's dangerous" option and screw it all to a slab of aluminum as a temporoary trial and see what you think.
Personally what I would do is bite the bullet and buy a used NAP250 complete (of whichever type you like CB/Olive/250.2), try it out for a while and then sell the one you don't want, you won't lose much if anything reselling NAPs if they haven't been messed with. If buying used take a look inside to see whats really in there, or ask for photos of the inside or a return policy - there are lots of butchered naim amps out there.