I don't think you can go far wrong with New forms by Roni Size. It's a classic and has the fabulous Brown paper bag on it, which is a must listen track if you like a bit of DnB.
Good point, you definitely want the vocal mix.Get the 2CD set, otherwise you don't get the vocal version of 'Brown Paper Bag'.
Time for some Baptazia:
The full set by Skibadee and Ruffstuff (that the audio from the second video is lifted from) is very good...
https://www.mixcloud.com/areyoudim/ruffstuff-with-skiba-fun-eksman-herbzie-kool-fm-february-2007/