The knobs are aluminium alloy and easy to refurbish - speaking from experience.
After removing them, dip them in some paint stripper such as the commonly available Nitromors.
Let it do its bit, using wire wool and a second application if necessary.
After cleaning, apply several light coats of a satin black aerosol,paint, whilst supporting the knobs on large screws or bolts.
The centring groove can then be carefully reinstated when paint dry, by use of a junior hacksaw blade.
Easy to get good results.