Your school lab was able to obtain white phosphorus and boil it in caustic soda under a CO2 atmosphere and then collect into hydrogen iodide and then heat in KOH? Impressed....
That said we used to make a contact explosive at lunchtimes (our sixth form lab was our classroom so we were unsupervised). Our teacher was most impressed....
School must be much less fun nowadays.
The phosphine 'gig' was a small part of one of the legendary Christmas lectures given by my sometime Chem teacher who was known unofficially as 'Dinky' Dunn. He was ably assisted by other members of the teaching staff.. and the assistants. I don't recall the method for the phosphine but I recall it bubbling up from under liquid and quietly igniting. Dinky used it as a source of ignition for numerous other tricks during the lecture.
Also on the same day he casually placed a water filled glass ampoule over a bunsen flame and covered the lot with a gauze cylinder. Naturally most of us knew what would happen.. but not when.... He then continued with other stuff as the tension rose. The resulting 'loud report' still took all of us lads by surprise, but Dinky seemed unphased.
He was quite mad....
Another trick was to put a petroleum soaked rag at the top of a piece of guttering propped against a window sill .. with a burning candle at the bottom. Descending vapour ignited and sent a flame up to the cloth., which was extinguished with CO2, but the candle wasn't.. and so on.. Many other explosions, bangs and flashes were featured.
Another spectacular one.. if I've got this right, was to throw a small beaker each of nitric acid and ammonia into a sink together. The resulting reaction sent clouds of white Ammonium Nitrate 'smoke' around the lab.
Naturally, neither pupils nor staff wore any protective gear. This was around 1963-4.
Dinky also demonstrated the explosive potential of finely divided combustible materials such as flour, coal dust etc.. He used fungal spores called 'Lycopodium Spores' (Which I have since speculated come from one or other of the 'Lycoperdon' species of puff ball. He simply blew a load of the spores through a long glass tube and over a bunsen flame. The resulting flamethrower effect removed the eyebrows of a couple of lads in the front row...
As for contact explosives. Sounds like Nitrogen Tri-Iodide. Easily made by dissolving iodine crystals in excess ammonia. The resulting brown precipitate is best kept under the ammonia until needed. We used to make the stuff and carry it around in small bottles. Then use a small wooden 'spill' to dredge a bit out and place it wherever it would cause mischief once dried. Shop door handles.. Vending machines.. wherever. We were evil little sods in our youth.
To be honest I do remember a demonstration that could have been phosphine production in my school in the early 70s - but that was a boys grammar school with amazing science facilities.
Yes. I too attended a superbly equipped school with separate junior and senior labs for Chem, Phys and Biol, plus a lecture theatre. Also fully equipped metalwork shop.. complete with forge and all blacksmithing tools, welding and brazing kit, lathes, shapers and other machine tools. Also similarly well equipped woodworking shop.
We were very lucky.