I'd be interested to know the details of how you get on with that, along with results. Trying to measure RF on the mains faces a number of difficulties.
First, the question of how to do so safely and not electricute yourself or fry the kit, whilst passing though the RF.
Secondly, how to measure all the various possible modes given 3 wires and some mix of common and difference modes.
Thirdly, the problem that you'd need some idea of the impedances - e.g. know the current level of the RF as well as the voltages.
Don't worry, I had no intention of directly connecting to the mains
Simply looking at an amps PSU transformer outputs just to get an idea of whats coming through. If something is then insert a funky mains cable and a proper RF filter to see what happens. A simple comparative test.
Could use a SMPS and Home plug network adaptor as "typical" sources of noise.
BTW I know from experience how easily Home plug signals are killed by anything nearby with a filter